| Alumina
Hydrate AI(OH)3
— Used as a source of alumina in glazes, alumina hydrate
promotes opacity and mattness and increases hardness and
durability. Very refractory. It can also be used in kiln wash or
to protect kiln furniture in salt firings.
Barium Carbonate BaC03
— The best way to introduce barium oxide in glazes, barium
carbonate functions as a high temperature flux. It can produce
satin matt glazes, but an excess will cause a rough, dry glaze
surface. TOXIC.
Bentonite (325 mesh) — A
highly plastic clay which is used in small amounts as a
plasticizer in clay bodies and a suspension agent in glazes. More
than 3% can cause cracking of the unfired glaze layer due to the
high drying shrinkage rate.
Bone Ash Ca3(PO4)2
— Typically made from ground, calcined animal bones, bone ash is
a source of calcium phosphate. It is used as a flux in clay bodies
- notably Bone China, which is known for its thinness and
translucency. Also used as an opacifier in glazes and to assist in
formation of opalescence (as in Chun glazes).
Borax Na2O•2B2O3
— Source of Boric Oxide and Soda in glazes. Small amounts can
increase fluidity of a glaze; larger amounts can lower the
maturing temperature.
Calcium Carbonate CaCO3
— (see Whiting)
CER Veegum — (Glaze
Hardener) Used in glazes as a suspending agent, viscosity
stabilizer and surface hardener (for safer handling of unfired
glazed ware). Recommended use:
add 1.0% to 1.5% based on the dry weight formula. Disperse in
water or add directly to dry mix.
Chrome Oxide (Green) Cr2O3
— A powerful and versatile glaze colorant that can produce a
variety of colors including green, yellow, pink, brown, and red -
depending upon glaze formula, atmosphere, and temperature of
firing. At temperature above cone 6, chrome oxide becomes volatile
and may affect adjacent ware in the kiln.
CMC Powdered Gum — An
organic cellulose gum used in slips and glazes as a binder,
thickener, and suspension agent. Recommended
use: Mix 1 to 2 tablespoons per gallon of warm water
and let stand for 24 hours. Use approximately one part of this CMC
Solution to 2 parts water when mixing a glaze to improve
brushability. Use lesser amounts for dipping, pouring or spraying
glazes. (CMC will increase drying time which is not always
beneficial to these application techniques).
Cobalt Carbonate CoCO3
— Used as a slip and glaze colorant, cobalt carbonate produces
various shades of blue or purples where manganese is present.
Because of its extremely fine particle size, it is more easily
dispersed in glazes than cobalt oxide.
Cobalt Oxide Co3O4
— Cobalt oxide is the
most powerful ceramic pigment available. Used in slips and glazes
in very small amounts, it produces strong blue colors. Because of
its intense coloring power and larger particle size, it can cause
a speckled effect.
Colemanite — (see Gerstley
Borate)
Copper Carbonate CuCO3
— A versatile, fine particle glaze and slip colorant which can
produce greens, blues, or reds depending upon glaze composition
and firing conditions.
Copper Oxide (Black) CuO —
More concentrated than copper carbonate, copper oxide is a strong
colorant and a flux. In an oxidizing or neutral atmosphere it
produces greens. Under reduction conditions red colors can be
obtained. When used in an alkaline glaze copper oxide gives a
turquoise blue color. Above 1900 degrees F copper oxide becomes
increasingly volatile and can affect the color of other glazed
pieces in the kiln.
Copper Oxide (Red) Cu2O
— Made by heat treating Black Copper Oxide. Red Copper is
insoluble in water, making it more difficult to work with.
Cornwall Stone (Cornish Stone) —
An English feldspathoid used as a flux in clay bodies and as a
major constituent in glazes. Like feldspar, Cornwall Stone
introduces the fluxes potash, soda and lime into a glaze, but with
more alumina and silica than is introduced by feldspar.
Darvan® No. 7-N — A
long-chain sodium polyelectrolyte best suited to deflocculate low-fire,
white “hobby” clays. It produces slips with a long
casting range, and excellent mold-release properties. Ware can be
removed as soon as 1-2 hours (depending on size) or left as long
as 6-24 hours (provided that the drainhole is covered). This
allows larger and/or more intricate forms extra set-up time for
safer handling and reduced warpage. Slips made with Darvan® No.
7-N have an increased shelf life because they don’t thicken or
become thixotropic upon standing (a common problem with many “hobby”
slips). During casting, there is minimal absorption of Darvan®
No. 7-N by the plaster resulting in greatly increased mold-life as
well as scrap that can be easily reclaimed - sometimes by adding
only water. Darvan® No. 7-N is very powerful requiring only a .5
to 1% addition (based on dry body weight) to the formula. Even so,
adding excess Darvan will not cause the slip to re-flocculate. In
addition, Darvan® No. 7-N is an excellent deflocculant/dispersing
agent in glazes to be applied by spraying, providing increased
fluidity without the addition of excessive amounts of water, and
keeping the materials evenly-dispersed in the glaze while you
work.
Darvan® No. 7-N has a shelf life
of 1 year or more if stored in a tightly closed container.
Temporary freezing will not effect its properties; however, the
thawed material must be thoroughly re-mixed before using.
Darvan
811 — A short-chain sodium polyelectrolyte used to
deflocculate Mid to High Fire Porcelain and Stoneware slips
as well as Low-Fire Red casting slips. Darvan 811 has many
of the same benefits as Darvan No. 7: Ionger casting range,
increased mold life, easy reclaimability and improved viscosity
stability. In addition, Darvan 811 also reduces “hard spots”,
and eliminates calcium/silica scum for better glaze adhesion.
Darvan 811 can also be used in glazes as a deflocculant/dispersing
agent to improve working properties during spray application. It
has a shelf life of 1 year or more and is not adversely effected
by short-term freezing. Thaw completely and re-mix thoroughly.
Deflocculant — Material
that acts on the molecular structure of clay causing clay to flow
as a liquid without the addition of excessive amounts of water.
Primarily used in the production of casting slips to create and
maintain fluidity without the increased shrinkage and weakness
that excess water will cause in the resulting greenware. See also
Sodium Silicate, Darvan No. 7 & Darvan 811.
Dolomite CaMg(CO3)2
— Dolomite is a naturally occurring mineral that contains
calcium carbonate and magnesium carbonate. It is used as a flux in
high temperature glazes wherever both magnesia and lime are
required.
Feldspar, Custer — A
potash feldspar used in both clay bodies and glazes. It can
function as a flux or as a refractory depending upon formula and
firing temperature.
Feldspar, Kona F-4 — A
soda feldspar used in clay bodies and glazes where a sodium flux
is required.
Feldspar, G-200 — A potash
feldspar used in glazes and clay bodies.
Flint, Silica, Silicon Dioxide
SiO2 —
The fundamental constituent of glazes and component of clay and
other ceramic raw materials. Used in glazes, flint will raise the
maturing temperature, increase the viscosity of the melt, and
increase hardness and craze-resistance. The addition of silica to
clay bodies makes the fired clay harder and more durable and
improves glaze fit.
Frits — Frits are combined
raw materials that are mixed, fired, melted, crushed and ground
into a powder. The reason for fritting is to render soluble
materials insoluble; decrease toxicity of raw materials such as
lead, barium and zinc; to reduce fusion point of glazes; and to
avoid volatilization of unstable substances. Frits are often used
in glazes as fluxing agents but can also be used in slips and clay
bodies. (See chart for composition).
*Gerstley Borate 2CaO•3B2O3•5H2O
— A sodium/calcium/borate compound used as a flux in glazes. It
is used to introduce boric oxide in an insoluble form and as a
more stable substitute for colemanite.
*Please Note: Gerstley Borate is
no longer mined: CALL for information
on Substitutes.
Grog — Ground, fired clay
added to clay bodies to improve workability and strength and to
give texture. The addition of grog also reduces shrinkage, warpage,
and cracking in drying and firing.
Ilmenite FeO•TiO2
— The ore of titanium and iron. Granular ilmenite is used to
produce a speckled effect in clay bodies and glazes. In small
amounts it can promote or “seed” the growth of crystals in
glazes - especially those containing rutile.
Iron Chromate FeCrO4
— Form of Iron usually used when darker browns and red-browns
are desired.
Iron Oxide (Red) Fe2O3
— Ferric oxide. Generally used as a colorant in clays and glazes
where iron is required. It produces a broad range of color - from
yellows, browns, red-browns, and blacks in oxidation to grays,
blues, greens, and blacks in reduction. Red iron has a finer
particle size than black iron which makes it disperse more easily
in a glaze. In mid-high temperature ranges iron oxide will act as
a flux, noticeably lowering the firing range of glazes.
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Iron
Oxide (Black) FeO — Ferric oxide. Produces the same range of
colors as Red Iron when used in glazes but is preferred by many
potters when making Celadon glazes for Reduction firing.
Kiln Wash — A refractory
mixture of kaolin and flint or alumina applied to kiln floors and
furniture to prevent adhesion of melted glaze.
Lithium Carbonate Li2CO3
— A slightly soluble source of lithium. When used as a flux in
glazes it can extend firing range, reduce thermal expansion, and
promote brilliant colors.
Magnesium Carbonate MgCO3
— This is used in glazes as a source of magnesium oxide. A
refractory at low temperatures, it becomes an active flux at high
temperatures. Magnesium carbonate produces matt surfaces,
increases glaze viscosity, and improves adhesion of glaze to clay.
Manganese Dioxide MnO2
— A fine particle ceramic colorant which usually produces browns
in glazes but can give purples in combination with cobalt or
alkaline fluxes.
Molochite — A white
porcelain grog. Reduces shrinkage, warpage, and cracking, while
maintaining color in white clay bodies.
Nepheline Syenite K2O•Na2O•4AI2O3•9SiO2
— A useful substitute for feldspar, nepheline syenite melts at a
lower temperature. It is widely used as a flux in both clay bodies
and glazes.
Nickel Carbonate NiCO3
— When used alone as a glaze colorant, nickel carbonate usually
produces greenish or brownish grays. It is especially useful as a
modifier for brighter colorants to produce more muted tones.
Nickel Oxide (Green) NiO —
More concentrated than nickel carbonate, nickel oxide is used in
small percentages to produce mute colors in glazes. It is
refractory and can raise the maturing temperature of glazes if
used in large amounts.
Nickel Oxide (Black) Ni2O3
— Reverts to Green Nickel at around 1100°F when used in a glaze
producing very similar results. However, increased amounts may be
necessary if substituting Black for Green in a recipe.
Nylon Fibers (Dupont P105)
— A fiber which can be added to clay bodies to increase wet
strength. Especially useful for handbuilding large slab forms, the
fibers create an inner structure in the clay allowing for easier
handling of larger slabs. The fibers are approximately ½ inch
long and burn out during firing. Recommended
use: Add 1.5% to 2% by weight. Fibers are most easily
added to dry mix but can be wedged into wet clay if necessary.
Ochre, Yellow — An iron
oxide ore used as a colorant in slips, clay bodies, and glazes.
Produces colors similar to iron oxide.
Plaster, Pottery (K-59) —
The standard of the industry, equivalent to No. 1 Pottery Plaster.
Recommended for most slip casting applications for strong,
long-lasting molds. Measuring Guidelines:
For slipcasting molds, throwing bats and wedging tables, a good
water to plaster ratio is 1:1-3/8 by weight. Using 1 Lb. as the
weight of 1 PT of water, some general ratios are:
1 PT water to 1
Lb 6 oz dry plaster
1 Qt. water to 2 lbs 12 oz dry plaster
1 Gal water to 11 Lbs dry plaster
To estimate how much water you’ll
need, use this guideline:
1 Qt.
water for every 80 cu. ins. of mixed plaster.
Therefore, compute the volume of your form in cu. ins. (L”xW”xH”)
and divide by 80; this equals the # of Qts. of water required). Mixing
Instructions: Measure the appropriate amount of water
into a large container and the correct amount of plaster as
computed above in a separate container. Slowly sift or sprinkle
the plaster evenly over the surface of the water and allow to
sink. You should see a noticeable increase in the length of time
the plaster floats on the surface before sinking as additions
continue. When all the plaster is added and submerged, mix slowly
but thoroughly - be sure to break up all chunks and try not to
introduce extra air into the mix. (Use your hand or a power mixer
on a low setting). Continue mixing until the plaster thickens
slightly (until a finger drawn across the surface leaves a trace
trail), then pour slowly into your form. Tap or lightly shake the
form to bring air bubbles to the surface. Let set, remove from
form and dry completely before using.
Pyrophyllite Al2O3•4SiO2•H2O
— A hydrated aluminum silicate used in clay bodies to decrease
thermal expansion, shrinkage, and cracking and to extend firing
range.
Rutile TiO2
— A natural ore containing titanium dioxide and a small amount
of iron. Used as a slip and glaze colorant, rutile produces
creams, tans and browns in oxidation and various bright oranges
and blues in reduction. It tends to produce mottled or broken
colors, increase opacity, and promote the growth of crystals in
glazes.
Silica — (see Flint)
Silica Sand — A very
coarse form of silica used to add texture and strength to clay
bodies.
Silicon Carbide (250 mesh) SiC
— In powdered form, used as a glaze ingredient for special
effects such as crater glazes and localized reduction.
Silicon Carbide - Ultrafine
(1000 mesh) SiC — Specially fine-ground for improved
dispersion. Recommended for producing more even, consistent
localized Reduction effects such as are required to produce “Oxidation
Copper Reds.”
Sodium Silicate — A
water-soluble solution of Soda and Silica traditionally used to
deflocculate casting slips. Often used in conjunction with Soda
Ash, it is equally effective in both high and low temperature
slips. Care must be used when using Sodium Silicate because it
will actually re-flocculate the slip if too much is added. Sodium
Silicate is also readily absorbed by plaster leading to
deterioration and the eventual breakdown of slipcasting molds.
Soda Ash Na2CO3
— Sodium Carbonate. Frequently used as a soluble deflocculant in
slip-casting bodies, it increases strength and reduces shrinkage.
Spodumene Li2O•AI2O3•4SiO2
— A lithium feldspar used in glazes to reduce shrinkage and
lower vitrification temperature. In clay bodies it decreases
thermal expansion.
Strontium Carbonate SrCO3
— A glaze flux similar to Whiting which promotes more craze and
scratch resistant glaze surfaces. Currently a popular substitute
for Barium Carbonate in glazes (.75 parts Sr to 1 part Ba is a
recommended starting point for testing).
Superpax ZrO4•
SiO2
— A fine-particle zircon opacifier used in slips and glazes. Discontinued
- substitute Zircopax Plus.
Talc 3MgO•4SiO2•H2O
— Useful as a flux in low
temperature clay bodies and in glazes at both high and low
temperatures. Also functions as an opacifier in glazes and reduces
thermal expansion.
Tin Oxide SnO2
— Dependable and widely used as a glaze opacifier. Tin oxide has
a refractory effect on glazes and can increase craze resistance.
Titanium Dioxide TiO2
— Used primarily as an opacifier in glazes, titanium dioxide
produces matt surfaces. It is also used as a seeding agent in
crystalline glazes. (Rutile is titanium with iron impurities).
Umber, Burnt — A hydrated
ferric oxide with manganese dioxide and clay. It can be used as a
slip or clay body colorant and produces a reddish-brown color.
Veegum-T — An iron-free
colloidal magnesium aluminum silicate used as a plasticizer-lubricant
in white clay bodies. A good binder for extruder bodies. Veegum T
can also be used as a suspending agent for glazes. Recommended
use: add 0.5% to 1.5% based on the dry weight formula. Should be
used in water as a dispersion addition.
Volcanic Ash (Pumice) — A
naturally occurring, fine particle material used in glazes to
replace feldspar and flint. Single color changes may result from
the iron oxide content of the ash.
Wax Resist — Water-soluble
wax emulsions used to resist glazes (underglaze, stains, etc) on
footrings, lid flanges and lids or for masking specific areas of a
piece for multi-layered glazing techniques. Once applied, wax
cannot be removed except by firing off in the kiln.
Whiting CaCO3
— Calcium carbonate. Whiting is a widely used source of lime in
glazes and a primary high temperature flux.
Wollastonite CaSiO3
— A naturally occurring calcium silicate; wollastonite is used
in both clay bodies and glazes to reduce drying and firing
shrinkage and improve fired strength.
Zinc Oxide ZnO — Generally
used as a flux in high temperature glazes, zinc oxide lends
opacity and encourages crystal growth when used in large amounts.
A common constituent of matt glazes, it also has a marked effect
on colorants, promoting brilliance with copper and dulling iron
and chrome. Zinc oxides can assist in reducing crazing of glazes.
Not recommended for use with some ceramic stains.
Zircopax ZrSiO4
— A zirconium silicate used as a slip and glaze opacifier. Discontinued
- substitute Zircopax Plus.
Zircopax Plus — Current
substitute for Superpax and original Zircopax. A fine-particle
zirconium silicate used as a glaze and slip opacifier. Disperses
very easily. Substitutes 1:1 for Superpax; may require less when
substituted for original Zircopax.
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